Hollow core coaxial cables and methods of making the same

ABSTRACT

Disclosed and claimed herein is a hollow core coaxial cable, having a dielectric capillary with an inside wall and an outside wall, an inner conductive layer on the inside wall of the hollow core coaxial cable and an outer conductive layer on the outside wall of the hollow core coaxial cable, the conductive layers may be patterned. Further disclosed is a method of making the hollow core coaxial cable. Further disclosed are holey fiber coaxial cables, having a holey fiber capillary having an inside wall and an outside wall, an inner conductive layer on the inside wall of the hollow core coaxial cable and an outer conductive layer on the outside wall of the hollow core coaxial cable, the conductive layers may be patterned.

FIELD OF THE INVENTION

This disclosure is in the field of high frequency coaxial cables capableof isolating and transmitting signals in the microwave and millimeterwavelength ranges. More particularly, described and claimed herein arehollow core coaxial cables and waveguides capable of transmitting suchhigh frequency signals and a method of making the same.

BACKGROUND

Coaxial cables are typically manufactured by forming, over a centerwire, a molded dielectric, and forming a braided outer conductor overthe dielectric. Alternatively it may be manufactured by inserting acenter wire conductor within a hollow braided wire (or some otherflexible metal tubing) with spacers. The dielectric spacers or shieldingthat run down the length of the cable prevents electrical contact of thecenter conductor to the outer conductor and holds a pre-defined distancebetween the center conductor and the outer conductor. The electricalterminals of the center conductor and the outer conductor are typicallyconnected to a source generating microwave signals or power in order totransmit electrical signals or energy effectively through the cable.

In such cables the center conductor is usually a solid wire. Cables withhollow conductors have been disclosed, for example, in Guilbert et al,U.S. Pat. No. 5,006,825 (1991), and Ditscheid et al, U.S. Pat. No.3,600,709, (1971). However, the hollow core coaxial cables described inthese patents tend to be large, inflexible, and expensive, and do notlend themselves easily to miniaturization. For applications where a verysmall diameter cable is required, the existing techniques do not scaledown well in size, for example, to cable diameters below 2 mm, 1 mm, or0.3 mm.

In addition, hollow glass waveguides for transmitting mid-infraredwavelengths of between 2.5-25 μm have been constructed based on hollowglass fibers having inner diameters of between 250-1000 μm with aconductor such as silver coated on the inside wall of the fiber atthicknesses from 0.2-0.4 μm. The conductor is then coated with thinlayers of dielectric materials such as polyimides, aluminum oxide,titanium dioxide, silicon dioxide, zinc chalcogenides (oxides, sulfides,selenides, and tellurides) silicon nitride, compound semiconductors andvarious metal halogen compounds, including silver chloride, silverbromide and silver iodide. For example, Matsuura et al., in “Opticalproperties of small-bore hollow glass waveguides,” Appl. Opt. 34, 6842(1995), describes the formation of silver coatings onto the inside ofglass capillaries having inner diameters as small as 250 μm andsubsequently coating the silver layer with silver iodide. Croitoriu etal, U.S. Pat. No. 4,930,863 (1990) discloses essentially the samestructure but larger and in tubes constructed of various polymers,including polyethylene, polytetrafluoroethylene, fluorinatedethylene-propylene, perfluoroalkoxy olefin as well as polyethylene,polypropylene, nylon 6, nylon 11, silicone rubber, rubber, polyvinylchloride and polystyrene. However, these disclosed waveguides are hollowand do not have a central conductor with a metalized outer conductorsurface separated by a dielectric and are therefore not coaxial nor inTEM (transverse electromagnetic mode). Hollow core waveguide techniquesare limited in their size as a function of the frequency of interest andat microwave frequencies that would require core diameters to range frommany centimeters across to millimeters across in the 10-100 GHz rangeunlike a TEM transmission line such as coaxial cables. In addition theyare limited in bandwidth to a particular frequency band based on thediameter of the waveguide.

Therefore, there remains a need for a flexible coaxial cable andwaveguide that is inexpensive and can be scaled down in size below thedimensions of hollow core waveguides, that can be easily fabricated, andthat can transmit RF, microwaves or millimeter waves. Moreover, thereremains a need for a flexible coaxial cable and wave guide that is madeinexpensively, with tight mechanical tolerances, and in which theconductor on the inner and outer surfaces are optionally removed to forma pattern or deposited to form a pattern leaving one or more clearareas. Such patterns can form antenna elements, inductors and othermicrowave components as well as fashion a port to allow entry and/oregress of high frequency signals through the dielectric withoutbreaching it. Moreover, there remains a need for a flexible coaxialcable and wave guide that can be formed into long lengths and cut intoprecise short lengths and which can be bundled in various ways,including flexible bundled cables, flexible ribbons and the like, andfor which existing manufacturing and cabling and connectorizationinfrastructure is largely capable of producing with high precision andlow cost.

DESCRIPTION OF THE DRAWINGS

FIG. 1 shows a cross section of a capillary made of a dielectricmaterial, 110, having an inner surface, 120, an outer surface, 100, anda hollow center, 130.

FIGS. 2( a) and (b) show a capillary similar to that in FIG. 1, bothlengthwise (a) and in cross section (b) after the inner and outersurfaces have had conductive materials applied to form a hollow corecoaxial cable. Shown in the figure are the conductive inner surface,220, the conductive outer surface, 200, dielectric material, 210, thehollow portion, approximately at the center, 230. A selected portion ofat least one of the outer conductive layer has been removed to form apattern, 240. Note that the pattern can be completely removed around thecircumference of the capillary or only partially removed. In likemanner, a portion of the conductive inner surface has been removed, 250.

FIG. 3 shows, in cross section, a holey fiber or photonic crystalcoaxial cable, having a central capillary, 330, and a plurality of outercapillaries, 320, surrounding the central capillary, wherein allcapillaries run approximately parallel to the long axis. The holey fibercoaxial cable is made from a dielectric material, 340. The inner surfaceof the central capillary is coated with a conductor, 300, and the outersurface of the holey fiber coaxial cable, 310, is also coated with aconductor.

FIG. 4 shows a cross section of a portion of a hollow core coaxial cablesimilar to that shown in FIG. 2 but with an additional polymerdielectric coating and optional conductor layer, wherein, optionally,selected portions of the conductive layers has been removed to formpatterns. Accordingly, FIG. 4 shows a capillary comprising a dielectricmaterial, 400, wherein the capillary is hollow approximately at thecenter, 405. On the inside wall of the capillary, there is a conductivecoating, 410, which is optionally removed to form a pattern, 420,optionally, leaving behind segmented portions of conductive coating,415. On the outside wall of the capillary, there is a conductivecoating, 425, which is optionally removed to form a pattern in the outerconductive coating, 435, and smaller segmented portions of conductivecoating, for example, 430. Further, the conductor coated capillary iscoated with a dielectric polymer coating, 460, which, in turn, isoptionally, coated with a conductor, 445, wherein portions of theconductor are optionally removed to form a pattern in the conductivecoating, 465, and smaller segmented portions of conductive coating, 470.In addition, FIG. 4 shows an optional conducting via structure, 440,which electrically connects the conductor, 445, on the outer layer ofthe dielectric polymer coating, 460, and the conductor, 425, on theoutside wall of the capillary. Also shown is an optional conducting viastructure, 455, which electrically connects the conductor, 425, in theoutside wall of the capillary with the conductor, 410, on the insidewall of the capillary. The via structures, 440 and 455, can be alignedor out of alignment as required. Similarly, the patterns in theconductors can be aligned or out of alignment as required. Moreover, theconductor patterns can have the conductive material removed around thefull circumference or on every face or they can be removed partially asrequired. Moreover, the pattern can be thought of either positively ornegatively, so that conductive materials can be deposited in the desiredareas or removed from the desired areas. Such patterned andinterconnected features enable coaxial or triaxial configurations withpatterns and shorts that allow one skilled in the art to produce one ormore of antennas, baluns, filters, etc.

FIG. 5( a) shows a connector, 500, used, in this example, to connect twohollow core coaxial cables. Shown in the figure is the central ferrule,505, with a longitudinal passage, 510. The capillary, 515, is showninserted into the longitudinal passage of the ferrule. FIG. 5( b) showsthe body of the ferrule, 505, in cross section, wherein the end face ofthe ferrule, 520, is optionally capped by a metal ring, 525, also shownin cross section. If the ferrule is a conductor, the metal ring may notbe required. Also shown in cross section are the hollow center of thehollow core coaxial cable, 535, the dielectric material of the hollowcore coaxial cable, 530, the inner surface of the hollow core coaxialcable coated with a conductor, 540, the outer surface of the hollow corecoaxial cable coated with a conductor, 545, configured such that thecoated outer surface of the hollow core coaxial cable is in electricalcontact with the metal ring, 525, that caps the end of the ferrule. Alsoshown is a metal insert, 550, in the end of the hollow core coaxialcable. The metal insert is itself hollow. Further shown in FIG. 5( b) isa second assembly, 555, that is similar to that in 505-550 butconfigured so as to be face-to-face with the first assembly. When thetwo ferrule-coaxial cable combinations are brought together, theconductor on the inner surface of the first capillary is brought intoelectrical contact with the conductor on the inner surface of the secondhollow core coaxial cable via their respective metal inserts. In likemanner, the conductor on the outer surface of the first hollow corecoaxial cable is brought into electrical contact with the conductor onthe outer surface of the first hollow core coaxial cable via contactwith their respective metal rings on the ferrule end faces or by theferrule end faces themselves if the ferrule is conductive. FIG. 5( c)shows a structure similar to FIG. 5( b) except that the end face of theferrule, 505, is generally semispherical. The capillary, having adielectric material, 530, a hollow core, 535, a conductor coated on itsinside surface, 540, and its outside surface, 545, is shown cementedinto the ferrule with cement, 560. The capillary is shown protrudingfrom the end of the semispherical ferrule so that it can make contactwith a mated ferrule. Also shown is a sealant for sealing the end of thecapillary, 565.

FIG. 6( a) shows a ribbon cable made from a plurality of hollow corecoaxial cables, 610, surrounded by a sheath which may comprise optionalbuffer layer, 615, further surrounded by a binder, 620, still furthersurrounded by an optional strength member, 625, and surrounded by ajacket, 630. FIG. 6( b) shows a plurality of hollow core coaxial cables,each having an inner surface coated with a conductor, 635. The capillaryis made of a dielectric, material, 640, and has an outer surface coatedwith a conductor, 645. In FIG. 6( b) the outer surfaces of the hollowcore coaxial cables make electrical contact with each other; thuscreating a common ground, which may aid in preventing ground loops.Alternatively, as shown in FIG. 6( c), there is shown a plurality ofhollow core coaxial cables; wherein each hollow core coaxial cable hasan inner surface coated with a conductor, 650. The capillary is made ofa dielectric, material, 655, and has an outer surface coated with aconductor, 660. The hollow core coaxial cables are each coated with adielectric sheathing material, 665, which insulates the respectiveconductors on the outer surfaces of the individual hollow core coaxialcables. In this configuration for example, the independent conductorscan provide independent DC power and/or lower frequency signals whilethe coax provides microwave signals or power transmission. Thecontiguous portions of the sheathing material on each hollow corecoaxial cable can be commingled with that from a neighboring cable toproduce a free-standing ribbon or not commingled to produce a loosearray.

In FIG. 7, such hollow core coaxial cables can be packaged in a largercapillary or tube or jacket. FIG. 7( a) shows, in cross section, abundle of hollow core coaxial cables with a sheath as in FIG. 6, shownhere as one layer, 700, individual hollow core coaxial cables, 705, anda central hollow core coaxial cable, 710. Such a package can also beused to provide a cooling loop to remove heat generated when the cablesare used to deliver power. In this case, as shown in FIG. 7( b), thereis a sheath as above, 750, individual hollow core coaxial cables, 755,and a central conduit, 760, that functions as an independent feed tubethat provides part or the cooling loop, using fluids such as gases,condensed gases or other cooling liquids, which are returned through theinterstitial voids between hollow core coaxial cables, 765, or viceversa. In addition, the center of one or more coax cables can also beused to delivery or receive one or more fluids.

FIGS. 8( a) and (b) illustrate a further use for hollow core coaxialcables. Shown in FIG. 8( a) is a hollow core coaxial cable, 800, havinga hollow core, 805, a conductor on the inner surface, 810, a conductoron the outer surface, 815, and a dielectric, 825, between theconductors, interfaced to a module that acts as a sensor, transducer oractuator, 820. In one example of its use, a laser is used to providepower to the module, 820, via the hollow core, 805. In this application,the hollow core acts as a waveguide to provide a low-loss power to themodule. Shown in FIG. 8( b) is a hollow core coaxial cable, 850, havinga hollow core, 855, a conductor on the inner surface, 860, a conductoron the outer surface, 865, and a dielectric, 875, between theconductors, interfaced to a module that acts as a sensor, transducer oractuator, 870. In one example of its use, a laser is used to provide anoptical signal to the module, 870, via the hollow core, 855. In thisapplication, the hollow core acts as a waveguide to provide a low-lossoptical signal to the module, 870. The optical signal is converted to anelectrical signal and is returned through one or both of the hollow corecoaxial cable conductors, 860, 865.

FIG. 9 shows a hollow core coaxial cable, 900, having a hollow core,905, a conductor on the inner surface, 910, and a conductor on the outersurface, 915, interfaced to a module that acts a sensor, transducer oractuator, 920. In one example of its use, a conducting wire, 925, isused to provide power or a signal to the module, 820. The wire, 925, maybe insulated to prevent electrical contact with the conductor on theinner surface of the hollow core coaxial cable, 905.

FIG. 10 shows how hollow core coaxial cables can function as switchedantennas. For example, FIG. 10 shows a bundle of nine hollow corecoaxial cables, 1000, with eight of the cables arranged generally on thevertices of an octahedron and one hollow core coaxial cable in thecenter. Four of the hollow core coaxial cables are selectively switchedon, 1005, and five of the hollow core coaxial cables, including the onein the center are selectively switched off, 1010. In this way, thedirectional properties of an RF signal can be selectively manipulatedusing the switched array. In the case of the example in FIG. 10, FIG. 10shows a plot of signal intensity as a function of the angle of azimuth,wherein a directional cardioid pattern is obtained, 1015.

DETAILED DESCRIPTION

As used herein, the conjunction “and” is intended to be inclusive andthe conjunction “or” is not intended to be exclusive unless otherwiseindicated. For example, the phrase “or, alternatively” is intended to beexclusive.

As used herein the term dielectric refers to a material property whereinthe conductivity of the material is less than about 10⁻¹⁰ Siemens permeter.

As used herein, when referring to a coating “on” a specific layer, itincludes a coating directly onto the specified layer and may include oneor more additional layers between the coating and the specified layer.

As used herein the term holey fiber refers to a fiber in which aplurality of holes, channels, capillaries and other voids aredistributed evenly or unevenly throughout at least a portion of thefiber.

As use herein term “via” refers to a channel connecting one or morelayers

Disclosed and claimed herein are hollow core coaxial cables, comprisinga dielectric capillary having at least one inside wall and at least oneoutside wall, at least one inner conducive layer on the inner wall ofthe capillary, and at least one outer conductive layer disposed on theouter wall of the capillary.

Further disclosed and claimed herein are methods of making a hollow corehigh frequency coaxial cable comprising: providing a hollow coredielectric hollow core coaxial cable having an inside wall and anoutside wall and a conductor disposed on the inside wall of the hollowcore coaxial cable; depositing a conductor on the outside wall of thehollow core coaxial cable.

Further, disclosed and claimed herein are holey fiber coaxial cables,comprising: a holey fiber dielectric capillary having at least oneinside wall and an outside wall; an inner conductive layer on the atleast one inside wall of the hollow core coaxial cable; and an outerconductive layer on the outside wall of the holey fiber capillary. Holeyfiber capillaries have been developed for photonic applications. Wherethe number of holes is large compared to the wavelength, it is alsoknown as holey fiber or photonic crystal waveguide. In the holey fibercapillary the dielectric constant, as well as the loss due to thedielectric, can be reduced by substantially reducing the effectivequantity of dielectric in the cross-section of the coaxial cable.Further the dielectric can be anisotropically distributed incross-section to produce effects such as polarization maintenance forthe propagating waves.

Further disclosed and claimed herein are multiple cables having two ormore hollow core coaxial cables forming a ribbon or bundled into agenerally round cross section. Selected hollow core coaxial cables ofthe multiple cable may further be switched. Further disclosed andclaimed are methods of non-symmetrically switching the hollow corecoaxial cables of the multiple cable to allow creation of a directionalantenna which allows for steering RF signal toward a preferreddirection.

Various modifications can be made to the hollow core coaxial cable. Forexample, the dielectric capillary or the holey fiber capillary can havea capillary cross section chosen from circular, oval, elliptical,triangular, square, rectangular, or hexagonal. The cross-section of theinner capillary hole and the outside of the dielectric can be of thesame shape or different shapes. For example, without intending to bebound by theory, the inside may be an oval or rectangular to preservepolarization if the inside diameter were used for sub millimeter orterahertz waveguiding. Both the inner conductor and outer conductor maybe shaped anisotropically to preserve one or more polarization statesfor the coaxial cable. Such techniques of formation of customcapillaries are known in the art of drawing optical fibers andcapillaries and typically involve first firming a larger scale glassstructure, tube, rod or assembly of glass tubes, plates, and rods and tofuse these elements together to form a larger scale preform containingthe desired cross-sectional elements. The preform is placed into a chuckin an elevated furnace where a portion of the preform melts and drops. Afiber remains attached between the preform and the molten drop and theglass capillary or fiber is then drawn on a capstan where the rate ofpull and rate of feed into of the preform into the furnace are carefullycontrolled based on feedback from measurements such as outside diameterof the fiber or capillary, which is typically measured using a lasermicrometer. Secondary polymer and metal coatings are often applied tothe fiber or capillary on the draw tower itself before spooling it.

Further, a selected portion of the inner conductive layer can be removedto form a pattern. Still further, a selected portion of the outerconductive layer can be removed to form a pattern.

Vias through the dielectric of the coaxial cable of various shapes maybe made by such method as, for example, machining, etching or removingby laser ablation at selected locations for various reasons such as toallow electrical shorting, fluid flow or a mechanical connection. Suchselective removal of the conductive layers and/or dielectrics can enablethe integral formation of antennas, impedance transformers, baluns, orenable the integration of mounting regions for switch elements, diodes,or other electrical, mechanical, sensing, or transducing elements.

Means for switching RF signals include mechanical switches,electromechanical switches, optical switches including opticaltransistors, modular bidirectional switches, coaxial switches, diodes,pin diodes or monolithic microwave integrated circuits (MMIC) andapplications specific integrated circuit (ASIC) based circuits,two-position switches, splitters, combiners, line couplers, switcharrays, stacked switch arrays, multiplexers, demultiplexers,electronically and optically switched pin diode arrays, equivalents ofthe above and combinations of the above. The choice of switching devicesor combinations of switching devices used for any particular applicationdepends to a large extent upon the frequency band of interest, powerlevels of the switched signals, and the speed of switching required.

Still further, the hollow core coaxial cable can have a polymer coatingon the outer conductive layer. Still further, the hollow core coaxialcable can have a conductive material disposed on the polymer coating.Still further, a selected portion of the conductive material disposed onthe polymer coating can be removed to form a pattern. The dielectriccapillary can comprise one or more dielectric materials such as, forexample, silica, fused quartz, fused silica, low —OH fused silica,glass, Teflon™, fluoropolymer, borosilicate glass, polyethylene,polytetrafluoroethylene, fluorinated ethylene-propylene, perfluoroalkoxypolyolefin, porous fluoropolymer, polypropylene, nylon 6, nylon 11,silicone rubber, rubber, polyvinyl chloride, polystyrene or otherdielectric materials that can be drawn, cast, molded, extruded, and/orotherwise formed. Still further, the inner conductive layer can compriseone or more metals chosen from silver, nickel, copper, gold, platinum,palladium, molybdenum, tungsten, tantalum or titanium. Still further,outer conductive layer can comprise one or more metals chosen fromsilver, nickel, copper, gold, platinum, palladium, molybdenum, tungsten,tantalum or titanium. Still further, the conductive material disposed onthe polymer coating comprises one or more metals chosen from silver,nickel, copper, gold, platinum, palladium, molybdenum, tungsten,tantalum or titanium. Other metals including alloys that are known inthe art of deposition through chemical, electrochemical, or vapordeposition means may be chosen.

Further disclosed and claimed herein is a method of making a hollow corehigh frequency coaxial cable comprising: providing a hollow coredielectric capillary having an inside wall and an outside wall and aconductor disposed on the inside wall of the capillary; and depositing aconductor on the outside wall of the capillary.

Various modifications can be made to the method of making a hollow corehigh frequency coaxial cable. For example, the method can furthercomprise removing a selected portion of the conductor disposed on theinside wall of the capillary. Further, the method can further compriseremoving a selected portion of the conductor on the outside wall of thecapillary. Removing a selected portion of the conductor disposed on theinside wall of the hollow core coaxial cable can be done by such methodsas, for example, ablating the conductor disposed on the inside wall ofthe hollow core coaxial cable with a laser, such as, for example, acarbon dioxide laser, a KrF Excimer laser, an ArF Excimer laser, an F2excimer laser, a frequency doubled neodymium YAG (yttrium aluminumgarnet) laser or a frequency tripled Yb:KYW (ytterbium in a matrix ofpotassium yttrium tungstate) laser. Removing a selected portion of theconductor on the outside wall of the hollow core coaxial cable can bedone by such methods as, for example, ablating a selected portion of theconductor on the outside wall of the hollow core coaxial cable with alaser, such as, for example, carbon dioxide laser, a KrF Excimer laser,an ArF Excimer laser, an F2 excimer laser, a frequency doubled neodymiumYAG laser or a frequency tripled Yb:KYW laser. The method can furthercomprise: applying a photoresist to the conductor on the outside wall ofthe hollow core coaxial cable; image wise patterning the photoresist;and etching a selected portion of the conductor on the outside wall ofthe hollow core coaxial cable.

Still further, depositing a conductor on the outside wall of the hollowcore coaxial cable is done by one or more of electroless plating,electroplating, sputtering, chemical vapor deposition or atomic layerdeposition. Still further, the method can further comprise applying apolymer coating to the conductor on the outside wall of the hollow corecoaxial cable. Still further, the polymer coating can be applied by dipcoating, spray coating chemical vapor coating or electrophoreticcoating. Still further, the method can further comprise depositing aconductor on the polymer coating. Still further, the method can furthercomprise removing a selected portion of the conductor on the polymercoating. Still further, the dielectric may be etched selectively orpatterned using one or more of the methods outlined above such as bylaser, patterning and etching, or by mechanical removal.

Capillaries and holey finer capillaries are understood to have insidewalls and outside walls. Hollow core coaxial cable walls comprisematerials that generally function as dielectrics in the desiredfrequency range. Although the cross sectional shape of the capillariesdepicted in FIG. 1-4 are generally round, it is understood that thecross sectional shape can be of any geometry such as square, rectangularor round, symmetrical or non symmetrical, to allow optimization for theapplication. The capillaries themselves may be porous or may comprisemany to thousands of hollow regions reducing the dielectric constant.

Capillaries can have different inner and outer diameters and dimensions,depending on the desired frequency range. When dimensions other thandiameters are specified, the measurement is made from flat face to flatface. Capillaries are coated with a polyimide or acrylic coating to givethem strength. Coating thickness from about 10 μm (microns) to about 100μm (microns) can be used. For example, inner diameters or dimensions canbe from about 25 to about 700 μm (microns). As a further example, innerdiameters or dimensions can be from about 75 to about 400 μm (microns).As a still further example, inner diameters or dimensions can be fromabout 75 to about 200 μm (microns). For example, outer diameters ordimensions can be from about 100 to about 850 μm (microns). Within thatrange, outer diameters or dimensions can be from about 100 to about 650μm (microns). Within that range, outer diameters or dimensions can befrom about 100 to about 360 μm (microns).

For this application, a hollow core holey fiber comprises a large centercapillary surrounded by a plurality of smaller capillaries, alsoreferred to as the holey cladding. In addition, the holey fiber can havean outer wall of fused silica or other dielectric material. Further theholey fiber may have a polymer coating of acrylic or polyimide. Theoutside polymer coating may have a thickness of from 10-100 μm(microns). The center capillary can have, for example, a diameter ofabout 5 to about 150 μm (microns). As a further example, the centercapillary can have a diameter 8 to about 100 μm (microns). As a stillfurther example, the center capillary can have a diameter from about 9to about 75 μm (microns). One useful way to characterize the smallercapillaries is the distance between centers. For example, the distancebetween centers of the smaller capillaries can be between about 1 toabout 20 μm (microns). As a further example, the distance betweencenters of the smaller capillaries can be between about 1.5 to about 15μm (microns). As a still further example, the distance between centersof the smaller capillaries can be between about 2 to about 10 μm(microns). A plurality of smaller capillaries surrounds the largercenter capillary, forming a holey cladding. One way to characterize theholey cladding in addition to the distance between centers measurement,supra, is the thickness of the holey cladding as measured from theoutside of the large center capillary to the edge of the outer wall. Forexample, the thickness of the holey cladding can be from about 10 toabout 200 μm (microns). As a further example, the thickness of the holeycladding can be from about 20 to about 100 μm (microns). As a stillfurther example, the thickness of the holey cladding can be from about25 to about 75 μm (microns). The thickness of the outer wall can be, forexample, from about 10 to about 200 μm (microns). As a further example,the thickness of the outer wall can be from about 15 to about 100 μm(microns). As a still further example, the thickness of the outer wallcan be from about 20 to about 50 μm (microns). The conductor thicknesseson the inside wall of the center capillary and the outside of the outerwall can be the same or different. As an example, conductor thicknesseson the inside wall of the center capillary and the outside of the outerwall can be from about 0.05 to about 20 μm (microns). As a furtherexample, the conductor thicknesses on the inside wall of the centercapillary and the outside of the outer wall can be from about 0.5 toabout 10 μm (microns). As a still further example, the conductorthicknesses on the inside wall of the center capillary and the outsideof the outer wall can be from about 0.75 to about 5 μm (microns). Theselection of the metal thickness may depend on the type of metal and thefrequency of the signal to be carried.

More than one hollow coaxial cable may be combined to form a ribbonstructure or may be bundled in a generally round cross section which canallow for a plethora of singles to propagate at the same time. Thehollow core coaxial cables of the multiple cable may be individuallyswitched in a non-symmetrical manner such that a radiation pattern maybe generated. The pattern may be detected which would allow for themultiple cable to be directed when the cable is not visible, such as,for example, in the human body as the multiple cable may allow theprecise positioning of a probe, a surgical device, an implant or thelike. The radiating multiple cable is especially useful when opticalmethods are hampered such as, for example, when there is a lot of bloodthat would blind optical devices.

For the purpose of the present disclosure, water is understood to bedeionized water, unless otherwise stated, however, deionized water isnot required. For the purposes of the present disclosure, conductorsgenerally function as such in the frequency range of interest. Thecoaxial cables and waveguides, described herein, may or may not beflexible but do function in straight or bent configurations. Duringplating of the inside wall, temperature is controlled by placing theoutside of the hollow core coaxial cable in a water bath having thedesired temperature. To heat at temperatures above about 80° C. thehollow core coaxial cable is placed in an oven.

It should be noted that, while the examples describe metal layers as theconductive material, other materials may also be used, such as, forexample graphene, carbon nanoparticles, organic conductive materials,such as, for example, polythiophene, polyacetylene, polypyrrole,polyaniline and the like, and other non-metallic conductive materialsknown in the art.

Plating the interior walls of capillaries can be accomplished byelectroless plating, or electroless plating followed by electroplating.These operations are usually accomplished by flowing solutions throughthe hollow core coaxial cable. In flowing solutions through capillaries,flow rates in ml/min are estimated according to Poiseuille's Equationfor a hollow core coaxial cable of circular cross section:

${FlowRate} = {{{\frac{\pi \cdot r^{4}}{8 \cdot \eta \cdot L} \cdot \Delta}\; P} = {{\frac{{\pi \cdot \Delta}\; P}{\eta \cdot L} \cdot 1.625} \times 10^{- 8}}}$Where r is the radius in μm, ΔP is the pressure in lb/in², η is theviscosity in centipoise and the length, L is in cm. For cross sectionsof other geometry, such as square, the radius is convenientlyapproximated by ½ the average flat-to-flat dimension.

Plating of the interior and exterior walls of capillaries can further beaccomplished by chemical vapor deposition (CVD) in which a hot precursorcontaining the desired metal atom is decomposed to the metal, thermallyor in a plasma. For example, Mo, Ta and Ti are deposited by low pressureCVD, from their pentachlorides according to the reaction:2 MCl₅+5 H₂→2 M+10 HCl

Tungsten is deposited from tungsten hexafluoride in one of two ways:WF₆→W+3 F₂WF₆+3 H₂→W+6 HF

Nickel, molybdenum, and tungsten are deposited at temperatures aboveabout 150° C. from their carbonyl precursors, Ni(CO)₄, Mo(CO)₆, W(CO)₆.Carrier gasses such as argon or nitrogen are used in variousconcentrations to control the deposition rate and morphology of themetal film.

Gold is deposited from, for example, Trifluorophosphine Gold(I)Chloride, usually, using hydrogen as a carrier gas at temperatures above110° C. To promote adhesion, another metal such as tantalum or platinumis deposited as a base.

Palladium is deposited from, for example, palladium(II) acetate at200-300° C., using H₂/He as a carrier gas.

Platinum is deposited from, for example,trimethyl(ethylcyclopentadienyl)platinum (C₂H₅C₅H₄)Pt(CH₃)₃, attemperatures above about 150° C., using argon as a carrier gas.

In use, signals can enter or be transmitted out of the waveguideconductively by direct coupling or through one or more openings in theconductive coatings, optimized for the particular frequency in use.

Pretreatment of fused quartz or silica inside and outside surfaces canbe accomplished using a solution of sodium hypophosphite (about 100gm/liter, buffered to pH 6-7 having a citrate or pyrophosphate buffer).Aqueous solutions of the organic boranes are also suitable such asdimethylamine borane, trimethylamine borane, diethylamine borane,triethylamine borane and pyridine borane. A suitable nonaqueousreductant solution, such as, for example di-isobutylaluminum hydride inhexane can also be used. Reducing gases may also be used such ashydrogen and carbon monoxide, optionally, with heating above about 100°C. Optionally, a dilute solution of buffered hydrofluoric acid (20/1 to40/1 dilution of the standard etching solution with dionized ordistilled water).

The following examples use glass or fused quartz capillaries or holeyfibers. Polymer capillaries, available from Paradigm Optics can also beused within the scope of this invention. Polymer materials used can bemade of polyethylene, polyvinyl chloride, polytetrafluoroethylene,polycarbonates such as polyethylene teraphthalate, polyperfluoroalkoxyethylene (PFA), and other fluorinated and non fluorinated polymers.Pretreatment of polymer based capillaries' inside and outside surfacescan be accomplished using a solution of sulphochromic acid at roomtemperature for a period of 20 minutes. Follow-on pretreatment canoptionally be accomplished using a solution of sodium hypophosphite(about 100 gm/liter, buffered to pH 6-7 having a citrate orpyrophosphate buffer). Aqueous solutions of the organic boranes are alsosuitable such as dimethylamine borane, trimethylamine borane,diethylamine borane, triethylamine borane and pyridine borane. Asuitable nonaqueous reductant solution such as, for example,di-isobutylaluminum hydride in hexane can also be used. Reducing gasesmay also be used such as hydrogen and carbon monoxide, optionally, withheating above about 100° C.

EXAMPLES

All examples are hypothetical.

Solution A

The following solution is used to prepare surfaces such as silica andrelated materials, prior to the application of the electroless platingsolutions: A solution of sodium hypophosphite is prepared (about 100g/dm³ sodium hypophosphite in water, buffered to pH 6-7 using apyrophosphate buffer).

Solution B

The following is used as a sensitizing agent for electroless plating: Asolution of SnCl₂/HCl in dionized water (SnCl₂, 70 g/dm³, HCl(concentrated ˜37%), 40 g/dm³) is prepared.

Solution C

The following is used as an activating agent for electroless plating: Asolution of PdCl₂/HCl in deionized water (PdCl₂, 1 g/dm³, HCl(concentrated ˜37%), 5 ml/dm³) is prepared.

Solution D

The following is used as a silver-Plating precursor: These materials aredissolved on order in a small amount of water: AgNO₃ (5 g),dodecylbenzene sulfonic acid sodium salt (30 mg), aqueous ammoniasolution (concentrated ˜28%, 25 ml). To the resulting solution, glacialacetic acid is added so that the final pH is reduced to 6-9. The volumeof the solution is then increased to about 100 ml by adding deionizedwater so that the Ag⁺ concentration is about 0.3 mole/dm³.

Solution E

The following is used as a reducer solution: A 3 mole/dm³ aqueous stocksolution of hydrazine hydrate (NH₂HN₂—H₂O) is diluted with deionizedwater to give a concentration of about 0.3 moles/dm³ solution.

Solution F

The following is used as a silver electroless plating solution: SolutionD precursor (25 ml) and Solution E reducer (6 ml) are blended anddiluted with water to make 100 ml of solution. The resulting solution isused immediately.

Solution G

The following is used as an alternative reducer solution: A 3 mole/dm³aqueous stock solution of an aldose sugar reducing agent such as glucoseis diluted with deionized water to give a concentration of about 0.3moles/dm³ solution. In this example, allose, altrose, mannose, gulose,idose, galactose, or talose can also be used in place of glucose.Moreover, lower molecular weight sugars such as glycolaldehyde,glyceraldehydes, erythrose, threose, ribose, arabinose, xylose, orlyxose can be used in the same molar proportion as well as formaldehydein the same molar proportion.

Solution H

The following is used as a silver electroless plating solution: SolutionD precursor (25 ml) and Solution G alternative reducer (using glucose asthe aldose sugar reducing agent, 6 ml) are blended and diluted withwater to make 100 ml of solution. The resulting solution is usedimmediately.

Solution I

The following is used as a nickel electroless plating solution, suitablefor plating at a temperature of 30-60° C. for example, about 54° C. togive a thickness of 0.75 μm: One (1) part sodium fluoride, 80 partssodium succinate, 100 parts nickel sulfate, and 169 parts sodiumhypophosphite are combined with 500 parts deionized water.

Solution J

The following is used as a copper electroless plating solution suitablefor plating at a temperature of 25-60° C. for example, about 54° C.: To250 ml of water are added, with stirring, cupric sulfate (CuSO₄-5H₂O—7.5g), triethanolamine (N(CH₂CH₂OH)₃—5.0 g), sodium hydroxide (NaOHsufficient to give a pH of 13.5—about 20 g), sodium cyanide (NaCN—0.5g), formaldehyde, 40% in water (H₂CO—40.0 g), water to make 1 dm³.

Solution K

The following is used as a copper electroless plating solution suitablefor plating at a temperature of 25-40° C. for example, about 32° C.: To250 ml of water are added, with stirring, cupric sulfate (CuSO₄-5H₂O—1.0g), potassium sodium tartrate (NaKC₄H₄O₆—2.7 g), sodium hydroxide (NaOHsufficient to give a pH of 13.5—about 20 g), sodium cyanide (NaCN—0.05g), formaldehyde, 40% in water (H₂CO—35.0 g), water to make 1 dm³.

Example 1

In this hypothetical example, a fused silica hollow core coaxial cableof generally square cross section, with an inner dimension of about 100μm (measured flat to flat), an outer dimension of about 300 μm (measuredflat to flat), a length of 10 cm, and coated with a polyimide coatingsuch that the outer dimension of the coating is about 383 μm, andwherein a portion of the polyimide coating is removed to reveal a baresegment of hollow core coaxial cable of length 0.5 cm, and wherein thebare segment of hollow core coaxial cable has coated segments on eitherlengthwise side, is provided by Polymicro Technologies, of Phoenix,Ariz. Solution A is urged through the capillary from a reservoir using aperistaltic pump, adjusted so that the average pressure is about 150lb/in² to achieve a flow rate of approximately 1.0 ml/min for a periodof about 10 min. Times are from first emergence from the hollow corecoaxial cable. In like manner, successive solutions are urged throughthe hollow core coaxial cable according to Table 1:

TABLE 1 Solution Flow Rate, ml/min Time, min Temperature, ° C. Waterrinse 1.0 10-20 25 Solution B 1.0 5 25 Water rinse 1.0 10-20 25 SolutionC 1.0 3 25 Water rinse 1.0 10-20 25 Solution F 1.0 5 15-30 Water rinse1.0 10-20 25

Example 2

Similar to example 1 except that the silver plating solution is SolutionH instead of solution F.

Example 3

Similar to example 1 except that the plating solution is Solution I at atemperature of 54° C. instead of solution F, to produce a hollow corecoaxial cable with nickel plated on the inside wall.

Example 4

Similar to example 1 except that the plating solution is Solution J at atemperature of 54° C. instead of solution F, to produce a hollow corecoaxial cable with copper plated on the inside wall.

Example 5

Similar to example 1 except that the plating solution is Solution K at atemperature of 32° C. instead of solution F, to produce a hollow corecoaxial cable with copper plated on the inside wall.

Examples 6-10

Any one of examples 1-5, having a portion of the protective polyimidecoating removed from the exterior wall of the hollow core coaxial cable,as described supra, is chosen. Removal of a portion of the conductivecoating on one or more of the interior walls is accomplished by laserablation using a 248 nm pulsed excimer laser, such as the Lumonics PM800laser (300 mJ, 1-30 W), although other lasers and wavelengths may alsobe used. In these examples, the flatness of the faces of the capillariesenables selective ablation of conductive material from one or moreselected sides.

Examples 11-20

Any one of examples 1-10 having a polyimide coating on some portion ofthe exterior wall of the capillary is chosen and the ends of the hollowcore coaxial cable are sealed with an epoxy-based formulation, such asSmartGel™, available from Nye optical Products of Fairhaven, Mass. Theouter wall of the hollow core coaxial cable is treated repeatedly withconcentrated sulfuric acid at 100-130° C. to remove the polyimidecoating and rinsed with deionized water. After rinsing, the hollow corecoaxial cable is placed in successive baths to plate the outer surfaceat times and temperatures according to Table 2:

TABLE 2 Solution Time, min Temperature, ° C. Solution B 5 25 Water rinse10-20 25 Solution C 3 25 Water rinse 10-20 25 Solution F 5 15-30 Waterrinse 10-20 25After plating, the metal clad hollow core coaxial cable is optionallycoated with a protective polyimide, acrylic or electrodepositedphotoresist coating or subjected to further processing.

Examples 21-30

Similar to examples 11-20, except that the plating solution is SolutionI at a temperature of 54° C. instead of solution F, to produce a hollowcore coaxial cable with nickel plated on the outside wall.

Examples 31-40

Similar to examples 11-20, except that the plating solution is SolutionJ at a temperature of 54° C. instead of solution F, to produce a hollowcore coaxial cable with copper plated on the outside wall.

Examples 41-50

Similar to examples 11-20, except that the plating solution is SolutionK at a temperature of 32° C. instead of solution F, to produce a hollowcore coaxial cable with copper plated on the outside wall.

Examples 51-90

The hollow core coaxial cable of any one of examples 11-50 is chosen.Removal of the metal coating from a portion of one or more of theexterior walls is accomplished by laser ablation using a 248 nm pulsedexcimer laser, such as the Lumonics PM800 laser (300 mJ, 1-30 W),although other lasers and wavelengths may also be used. In theseexamples, the flatness of the faces of the capillaries enables selectiveimage wise ablation of metal from one or more sides. Moreover, the openarea created by ablation can be aligned with the ablated portions of theinterior wall so that the open areas overlap or are masked respectively,as required for the particular use contemplated. Optionally, to protectthe hollow core coaxial cable, a polymer coating can be disposed on theoutside of the hollow core coaxial cable such as a polyimide or anacrylic or an electrodeposited resist, a suitable example of which isEAGLE™ 2100 ED Negative acting electrodeposited photoresist, along withits ancillary developer, EAGLE™ 2005 developer, available from the DowChemical Company. The resist is applied by direct current cataphoreticalelectro-deposition at a direct current potential of 70 Volts, bathtemperature 45° C., baked at 100° C. for 20 minutes and may be bulk orimage-wise photo-cured at a wavelength of 365 nm and a dose of 300-800mJ/cm², depending on the thickness of the coating.

Examples 91-95

Similar to examples 1-5 except that the polyimide coated hollow corecoaxial cable is circular in cross section with a length of 20 cm, aninner diameter of about 150 μm, and the pressure is about 95 lb/in², andadjusted to give a flow rate of about 1.5 ml/min, available fromPolymicro Technologies, of Phoenix, Ariz. As above, this hollow corecoaxial cable has a portion of its polyimide coating removed such that abare segment of hollow core coaxial cable is visible with coatedsegments on either lengthwise side.

Examples 96-100

Similar to examples 6-10 except that any one of examples 91-95, having aportion of the protective polyimide coating removed from the exteriorwall of the hollow core coaxial cable, as described supra, is chosen.Image wise removal of a portion of the metal coating the interior wallof the hollow core coaxial cable is accomplished by laser ablation usinga 248 nm pulsed excimer laser, such as the Lumonics PM800 laser (300 mJ,1-30 W), although other lasers and wavelengths may also be used.

Examples 101-110

Similar to examples 11-20 except that the capillaries from examples91-100 are used.

Examples 111-120

Similar to examples 101-110, except that the plating solution isSolution I at a temperature of 54° C. instead of solution F, to producea hollow core coaxial cable with nickel plated on the outside wall.

Examples 121-130

Similar to examples 101-110, except that the plating solution isSolution J at a temperature of 54° C. instead of solution F, to producea hollow core coaxial cable with copper plated on the outside wall.

Examples 131-140

Similar to examples 101-110, except that the plating solution isSolution K at a temperature of 32° C. instead of solution F, to producea hollow core coaxial cable with copper plated on the outside wall.

Examples 141-180

The hollow core coaxial cable of any one of examples 101-140 is chosen.Image-wise removal of the metal coating from a portion of the exteriorwalls is accomplished by laser ablation using a 248 nm pulsed excimerlaser, such as the Lumonics PM800 laser (300 mJ, 1-30 W), although otherlasers and wavelengths may also be used. In these examples, the circularcross section geometry of the hollow core coaxial cable does not enableselective image wise laser ablation from individual faces. The open areacreated by ablation can be aligned with the ablated portions of theinterior wall so that the open areas overlap or are masked respectively,as required for the particular use contemplated. Optionally, to protectthe hollow core coaxial cable, a polymer coating can be disposed on theoutside of the hollow core coaxial cable such as a polyimide or anacrylic or an electrodeposited resist, a suitable example of which isEAGLE™ 2100 ED Negative acting electrodeposited photoresist, along withits ancillary developer, EAGLE™ 2005 developer, available from the DowChemical Company. The resist is applied by direct current cataphoreticalelectro-deposition at a direct current potential of 70 Volts, bathtemperature 45° C., baked at 100° C. for 20 minutes and may be bulk orimage-wise photo-cured at a wavelength of 365 nm and a dose of 300-800mJ/cm², depending on the thickness of the coating.

Example 181

Any one of the polymer coated capillaries described in Examples 51-90 or141-180 can be used. The surfaces of the polymer coatings are treatedusing a dilute solution of sulphochromic acid at room temperature for aperiod of 20 minutes. Pretreatment is continued using a solution ofsodium hypophosphite (about 100 gm/liter, buffered to pH 6-7 with apyrophosphate buffer). After rinsing thoroughly with deionized water,the polymer coated hollow core coaxial cable is placed in successivebaths to plate the outer surface at times and temperatures according toTable 2. This produces a hollow core coaxial cable with three layers ofmetal.

Example 182

The hollow core coaxial cable with three layers of metal of example 181is subject to image wise laser ablation as described in Examples 141-180so that a portion of the metal coating is ablated.

Example 183

A glass hollow core coaxial cable of 300 μm inner diameter and 400 μmouter diameter and a silver coating on the inside surface of about 10 μmof thickness and an acrylic coating on the outside surface of 175 μm ofthickness (total outer diameter of about 750 μm) is provided byPolymicro Technologies, of Phoenix, Ariz. The acrylic coating is removedwith a gentle stream of acetone and the ends of the hollow core coaxialcable sealed with epoxy. The outer surface of the glass of the glasshollow core coaxial cable is treated using a solution of sodiumhypophosphite (about 100 gm/liter, buffered to pH 6-7 with apyrophosphate buffer) and rinsed thoroughly with water. Thereafter, theouter surface of the hollow core coaxial cable is treated sequentiallywith the solutions as in Table 2. A polymer coating is disposed on thecoaxial cable thus formed as described in, for example, Examples141-180. Optionally, the outer polymer coating can be coated once againwith metal as described supra in Example 181.

Example 184

A glass hollow core coaxial cable of 300 μm inner diameter and 400 μmouter diameter and a silver coating on the inside surface of about 10 μmof thickness and an acrylic coating on the outside surface of 175 μm ofthickness (total outer diameter of about 750 μm) is provided byPolymicro Technologies, of Phoenix, Ariz. A portion of the acryliccoating is removed with a gentle stream of acetone. The silver plated onthe inner surface is then ablated image-wise as described supra inExamples 96-100. The ends of the hollow core coaxial cable sealed withepoxy. The outer surface of the glass of the glass hollow core coaxialcable is treated using a solution of sodium hypophosphite (about 100gm/liter, buffered to pH 6-7 with a pyrophosphate buffer) and rinsedthoroughly with water. Thereafter, the outer surface of the hollow corecoaxial cable is treated sequentially with the solutions as in Table 2.Optionally, a portion of the silver on the outer surface is ablatedimage-wise as described in Examples 141-180. A polymer coating isdisposed on the coaxial cable thus formed as described in, for example,Examples 141-180. Optionally, the outer polymer coating can be coatedonce again with metal as described supra in Example 181 and portions ofthe metal removed image-wise from the outer surface of the polymercoating.

Example 185

Plating both the inside and outside surfaces: The hollow core coaxialcable is laid out in a vessel so that both open ends are covered whensubjected to the desired solution at the desired temperature. Thesolution is poured into the vessel and the vessel placed into a vacuumchamber. A vacuum of about 15 mm of mercury or less is applied so thatthe fluid infuses the inside of the hollow core coaxial cable. Thevessel is removed from the vacuum chamber, and allowed to stand for theprescribed amount of time. The hollow core coaxial cable is turned onend and placed on an absorbent mat so that the infused solution is drawnout. The hollow core coaxial cable is rinsed with dionized water severaltimes in the vacuum chamber as above and subjected to treatment with thenext solution or dried, as required. In this way, it is possible tosimultaneously plate the insides and outsides of one or morecapillaries.

Example 186

Thus a glass hollow core coaxial cable of 75 μm inner diameter ispretreated with Solution A according to the method of Example 185 andrinsed thoroughly according to the method of Example 185. Thereafter, insimilar fashion, successive solutions are applied as shown in Table 2.

Example 187

By way of example, a holey fiber capillary coaxial cable is fabricatedin the following way. A fused optical grade holey fiber with individualcapillaries of about 100 μm and with lapped or cleaved ends is obtainedfrom Newport Corporation of Irving, Calif. or NKT Photonics of Denmark.A plurality of individual capillaries in the holey fiber is obscuredusing an epoxy-based formulation such as SmartGel™, available from Nyeoptical Products of Fairhaven, Mass. The holey fiber is placed in a highpressure jig, fitted with an o-ring assembly such that the obscuredportions of the holey fiber face are on the upstream side of the jig.Solution A is urged through the remaining channels of the holey fiberfrom a reservoir using a peristaltic pump, adjusted so that the averagepressure is about 150 lb/in² to achieve a flow rate of approximately 1.0ml/min for a period of about 10 min. Times are from first emergence fromthe hollow core coaxial cable. In like manner, successive solutions areurged through the hollow core coaxial cable according to Table 1. Oncethe selected inner walls of the holey fiber, are coated with conductorand dried, the ends are fully sealed with SmartGel™ as above. After theSmartGel™ is cured, the hollow core coaxial cable is placed insuccessive baths to plate the outer surface at times and temperaturesaccording to Table 2. The obscured ends of the holey fiber are then cutusing a precision blade. The holey fiber coaxial cable is ready for useor further processing.

Example 188

Without intending to be bound by theory, the results of simulations ofdielectric loss for a holey fiber capillary coaxial cable wherein theconductor thickness is 1 μm (micron) and the length is 30 cm are shownin Table 3.

TABLE 3 Inside Wall, Outside Wall Frequency, gHz Dia., μm Dia., μmDielectric Loss, dB 0.915 100 500 ~0.7 0.915 200 1000 ~0.4 2.45 100 500~1.05 2.45 300 1000 ~0.6

Although the present invention has been shown and described withreference to particular examples, various changes and modificationswhich are obvious to persons skilled in the art to which the inventionpertains are deemed to lie within the spirit, scope and contemplation ofthe invention.

What is claimed is:
 1. A hollow core coaxial cable, comprising: a. aglass capillary having an inside wall and an outside wall providing ahollow core extending along a central axis thereof; b. an innerconductive layer disposed on the inside wall of the capillary; and c. anouter conductive layer disposed on the outside wall of the capillary. 2.The hollow core coaxial cable of claim 1, wherein the glass capillaryhas a cross section chosen from circular, oval, elliptical, triangular,square, rectangular, or hexagonal.
 3. The hollow core coaxial cable ofclaim 1, wherein the conductive layers may be the same or different andcomprise one or more metals chosen from silver, nickel, copper, gold,platinum, palladium, molybdenum, tungsten, tantalum or titanium.
 4. Thehollow core coaxial cable of claim 1, further comprising a polymerlayer, wherein the polymer layer has been disposed on the outerconductive layer and further comprising n additional conductive layersdisposed on the polymer layer; wherein n is 0-1.
 5. The hollow corecoaxial cable of claim 2, wherein a selected portion of at least one ofthe conductive layers has been removed to form a pattern.
 6. The hollowcore coaxial cable of claim 4, wherein a selected portion of at leastone of the conductive layers has been removed to form a pattern.
 7. Thehollow core coaxial cable of claim 4, wherein a selected portion of theglass capillary or polymer layer or both have been removed and a via isformed between at least two of the conductive layers; and wherein thevia between the conductive layers comprises an electrical connectionbetween the conductive layers.
 8. A multiple cable comprising aplurality of the hollow core coaxial cables of claim 4, wherein theplurality of hollow core coaxial cables form a ribbon or a bundle ofgenerally round cross section.
 9. The multiple cable of claim 8, furthercomprising at least one connector.
 10. The multiple cable of claim 8,further comprising means for switching signals into selected hollow corecoaxial cables.
 11. The multiple cable of claim 8, wherein the hollowcore coaxial cables are bound together.
 12. A method of use of hollowcore coaxial cables comprising: a. providing the multiple cable of claim11, configured to form an antenna; b. selecting one or more of thehollow core coaxial cables in the multiple cable to form a pattern; c.providing a signal to each of the selected hollow core coaxial cables.13. The method of claim 12, wherein the pattern provides a directionalantenna.
 14. A method of making the flexible, hollow core, coaxial cableof claim 1, comprising: a. providing a hollow core dielectric capillaryhaving an inside wall and an outside wall and a conductor layer disposedon the inside wall of the capillary and, b. depositing a conductor layeron the outside wall of the capillary.
 15. The method of claim 14,wherein depositing the conductor on the outside wall of the capillary isdone by one or more of electroless plating, electroplating, sputtering,chemical vapor deposition or atomic layer deposition.
 16. The method ofclaim 14, further comprising applying a polymer coating to the conductorlayer of the outside wall of the capillary.
 17. The method of claim 16,wherein the polymer coating is applied by dip coating, spray coatingchemical vapor coating or electrophoretic coating.
 18. The method ofclaim 16, further comprising depositing an additional conductor on thepolymer coating.
 19. The method of claim 18, further comprising removinga selected portion of at least one of the conductor layers.
 20. Themethod of claim 19, wherein removing a selected portion of at least oneof the conductor layers is done by ablating the conductor material witha laser, chosen from a carbon dioxide laser, a KrF Excimer laser, an ArFExcimer laser, an F₂ excimer laser, a frequency doubled neodymium YAGlaser or a frequency tripled Yb:KYW laser.
 21. The method of claim 19,wherein removing a selected portion of at least one of the conductorlayers is done by: a. applying a photoresist to the conductor layer onthe outside wall of the capillary, b. patterning the photoresist toexpose a selected portion of the conductor, and c. etching the selectedportion of the conductor.
 22. A holey fiber coaxial cable, comprising:a. a holey dielectric fiber having an outside wall, a center capillaryhaving an inside wall, and a plurality of outer capillaries arrayedaround the center capillary, each having an inside wall, the pluralityof outer capillaries disposed between the center capillary and theoutside wall; b. at least one conductive layer disposed on the insidewall of the center capillary; and c. a conductive layer on the outsidewall of the fiber.
 23. The holey fiber coaxial cable of claim 22,wherein the center capillary has a cross section chosen from circular,oval, elliptical, triangular, square, rectangular, or hexagonal.
 24. Theholey fiber coaxial cable of claim 22, wherein a selected portion of atleast one of the conductive layers has been removed to form a pattern.25. The holey fiber coaxial cable of claim 22, further comprising apolymer layer, wherein the polymer layer is disposed on at least one ofthe conductive layers or between at least one of the conductive layersand the dielectric.
 26. The holey fiber coaxial cable of claim 25,further comprising an additional conductive material disposed on thepolymer coating when the polymer has been disposed on the outerconductive coating.
 27. The holey fiber coaxial cable of claim 26wherein a selected portion of at least one of the conductive layers hasbeen removed to form a pattern.
 28. The holey fiber coaxial cable ofclaim 27, wherein a selected portion of the holey dielectric fiber orpolymer coating or both have been removed to form a via between at leasttwo of the conductive layers.
 29. The holey fiber coaxial cable of claim28, wherein the via between the conductive layers comprises anelectrical connection between the conductive layers.
 30. The holey fibercoaxial cable of claim 26, wherein the conductive layers may be the sameor different and comprise one or more metals chosen from silver, nickel,copper, gold, platinum, palladium, molybdenum, tungsten, tantalum ortitanium.